Gas Hydrates

Gas hydrates are crystalline solids with cage-like structures [clathrates] in which a hydrocarbon molecule is enclosed in a lattice of water molecules. Although they have the appearance of ice or snow, gas hydrates crucially form at pressures and temperatures above the freezing point of water.

Gas hydrates are of particular interest to the oil and gas industry as they can form at various stages of production where the crystals can agglomerate to form a blockage.

KAT’s 8 [500ml] Autoclaves and 16, [45ml] Non-Visual Rocking Cells are typically used for the evaluation of thermodynamic and kinetic hydrate inhibitors.

KAT’s 2 [40ml] sapphire tube, Visual Rocking Cells and [500ml] Autoclave with torque measurement unit are typically used for the evaluation of anti-agglomerant hydrate inhibitors.

Each hydrate test cell has a maximum working pressure of 2,900psi [200barg] and can be computer temperature controlled between 0 and +30°C [32 and 86°F]. Temperature and pressure data for each cell is monitored and logged by computer. In the case of the Visual Rocking Cells, the contents of each test cell are also captured using digital video cameras.

KAT has developed a range of standard gas hydrate test protocols in conjunction with both BP and Shell; however, KAT’s flexible control technology means that bespoke, client specific test methods to easily be achieved.

Fluid Analysis

KAT offers a suite of analyses to characterise crude oil and gas condensate samples and help assess the potential impact on production operations.SARA [latroscan]Separates the test fluid into four solubility classes: Saturate (Paraffin), Aromatic, Resin, and Asphaltenes using the Iatroscan…

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Asphaltenes

Asphaltenes are a natural constituent of many crude oils and may be precipitated in production systems when the crude’s natural solvency for them is reduced. Several factors including, pressure, temperature, and composition can change the stability of these high molecular…

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Separation

Foaming When produced and transported from the reservoir to processing facilities, fluids experience a drop in pressure. This will release dissolved gases that can cause the fluids to foam. Evolved gas is removed in a separator, but foaming can lead…

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Gas Hydrates

Gas hydrates are crystalline solids with cage-like structures [clathrates] in which a hydrocarbon molecule is enclosed in a lattice of water molecules. Although they have the appearance of ice or snow, gas hydrates crucially form at pressures and temperatures above…

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Oilfield Scale

Oilfield scale is the term used to describe deposits of insoluble inorganic minerals such as calcium carbonate, barium sulphate, and metal sulphides. In general, scale deposits occur when waters with different ion contents are mixed although pressure and pH can…

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Rheology

Dynamic Viscosity Dynamic Viscosity vs. Temperature curves for assessing the flow behaviour of a waxy [Non-Newtonian] fluid are produced at a range of shear rates corresponding to typical production flowrates during normal steady-state pipeline flowing conditions. As such, each curve…

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Wax Appearance

Waxes are generally defined as paraffinic material with carbon numbers greater than nC17. Waxes are present in oil as a distribution of molecular weights and thus exhibit a range of solubilities, precipitating over a range of conditions. Precipitation is temperature…

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Wax Deposition

The build-up of solid waxy layers onto cooled surfaces such as pipe walls is generally considered to be a temperature-dominated phenomenon. Several theories have been proposed to describe the effect and several commercial semi-empirical models have been developed to predict…

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Arn Acids

Napthenate Solids Naphthenate solids are naturally occurring oilfield fluid scales formed from reactions between a specific group of high molecular weight cyclic naphthenic ARN acids, also known as Tetra Protic Acids or Tetra-Acids, with dissolved divalent cations [such as Ca,…

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T-SEP®

Compared to the relatively high concentrations of nC10 – 20 in crude oils and gas condensates [analysed as unadulterated “Whole” sample] the concentrations of >nC30 can be relatively low and either close to or below the limit of detection /…

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